{"id":4261,"date":"2021-12-17T13:58:26","date_gmt":"2021-12-17T13:58:26","guid":{"rendered":"https:\/\/bioingenieria.zeus.umh.es\/unidad-de-quimica-organica\/"},"modified":"2022-02-22T09:48:51","modified_gmt":"2022-02-22T09:48:51","slug":"unidad-de-quimica-organica","status":"publish","type":"page","link":"https:\/\/bioingenieria.umh.es\/en\/unidad-de-quimica-organica\/","title":{"rendered":"Unidad de Qu\u00edmica Org\u00e1nica"},"content":{"rendered":"

[et_pb_section fb_built=”1″ fullwidth=”on” disabled_on=”on|on|on” admin_label=”Secci\u00f3n” _builder_version=”3.22″ disabled=”on”][et_pb_fullwidth_header title=”UNIDAD DE QU\u00cdMICA ORG\u00c1NICA” text_orientation=”center” content_max_width=”none” admin_label=”T\u00edtulo de anchura completa” _builder_version=”3.16″ background_color=”#26aa9f” button_one_letter_spacing_hover=”0″ button_two_letter_spacing_hover=”0″ button_one_text_size__hover_enabled=”off” button_two_text_size__hover_enabled=”off” button_one_text_color__hover_enabled=”off” button_two_text_color__hover_enabled=”off” button_one_border_width__hover_enabled=”off” button_two_border_width__hover_enabled=”off” button_one_border_color__hover_enabled=”off” button_two_border_color__hover_enabled=”off” button_one_border_radius__hover_enabled=”off” button_two_border_radius__hover_enabled=”off” button_one_letter_spacing__hover_enabled=”on” button_one_letter_spacing__hover=”0″ button_two_letter_spacing__hover_enabled=”on” button_two_letter_spacing__hover=”0″ button_one_bg_color__hover_enabled=”off” button_two_bg_color__hover_enabled=”off”][\/et_pb_fullwidth_header][\/et_pb_section][et_pb_section fb_built=”1″ disabled_on=”on|on|on” admin_label=”section” _builder_version=”3.22″ disabled=”on”][et_pb_row padding_mobile=”off” column_padding_mobile=”on” admin_label=”Fila” _builder_version=”3.25″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” max_width=”960px” make_fullwidth=”off” use_custom_width=”on” width_unit=”on” custom_width_px=”960px”][et_pb_column type=”4_4″ _builder_version=”3.25″ custom_padding=”|||” custom_padding__hover=”|||”][et_pb_text admin_label=”Texto” _builder_version=”3.27.4″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” use_border_color=”off” border_color=”#ffffff” border_style=”solid”]<\/p>\n

La Unidad de Qu\u00edmica Org\u00e1nica se dedica a la s\u00edntesis de mol\u00e9culas org\u00e1nicas con aplicaciones optoelectr\u00f3nicas y\/o biotecnol\u00f3gicas. Con este fin, utilizamos diversos andamios como ftalocianinas, perilendiimidas, diketopirropirrolos, fullerenos, nanotubos y otras nanoformas de carbono, grafeno, MoS2… que tras su modificaci\u00f3n estructural se transforman en valiosos bloques de construcci\u00f3n para la preparaci\u00f3n de c\u00e9lulas solares org\u00e1nicas o h\u00edbridas, sistemas fotosint\u00e9ticos artificiales, l\u00e1seres de colorantes org\u00e1nicos, sensores, agentes de imagen duales, metaloides…<\/p>\n

[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row padding_mobile=”off” column_padding_mobile=”on” admin_label=”Fila” _builder_version=”3.25″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” max_width=”860px” make_fullwidth=”off” use_custom_width=”on” width_unit=”on” custom_width_px=”860px”][et_pb_column type=”4_4″ _builder_version=”3.25″ custom_padding=”|||” custom_padding__hover=”|||”][et_pb_text admin_label=”Texto” _builder_version=”3.27.4″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” use_border_color=”off” border_color=”#ffffff” border_style=”solid”]<\/p>\n\n\n\n\n
Coordinador de la unidad<\/strong><\/td>\nFernando Fern\u00e1ndez L\u00e1zaro<\/td>\n<\/tr>\n
Contacto<\/strong><\/strong><\/td>\nfdofdez@umh.es<\/span><\/strong><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row padding_mobile=”off” column_padding_mobile=”on” admin_label=”Fila” _builder_version=”3.25″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” max_width=”960px” make_fullwidth=”off” use_custom_width=”on” width_unit=”on” custom_width_px=”960px”][et_pb_column type=”4_4″ _builder_version=”3.25″ custom_padding=”|||” custom_padding__hover=”|||”][et_pb_text admin_label=”Texto” _builder_version=”3.27.4″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” use_border_color=”off” border_color=”#ffffff” border_style=”solid”]<\/p>\n

GRUPOS<\/strong><\/h2>\n

El Instituto de BioIngenier\u00eda de la Universidad Miguel Hern\u00e1ndez cuenta con distintos grupos de Qu\u00edmica Org\u00e1nica:<\/p>\n

[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row padding_mobile=”off” column_padding_mobile=”on” admin_label=”row” _builder_version=”3.25″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” max_width=”860px” make_fullwidth=”off” use_custom_width=”on” width_unit=”on” custom_width_px=”860px”][et_pb_column type=”4_4″ _builder_version=”3.25″ custom_padding=”|||” custom_padding__hover=”|||”][et_pb_text admin_label=”Texto” _builder_version=”4.2.2″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” use_border_color=”off” border_color=”#ffffff” border_style=”solid”]<\/p>\n

S\u00edntesis Molecular<\/a><\/h2>\n

Desde su descubrimiento, las perilendiimidas (PDI) han atra\u00eddo mucha atenci\u00f3n gracias a su fuerte absorci\u00f3n de la luz visible, sus elevados rendimientos cu\u00e1nticos de fluorescencia y su estabilidad t\u00e9rmica, qu\u00edmica y fotoqu\u00edmica. Otra vuelta de tuerca se produjo con la llegada de la optoelectr\u00f3nica org\u00e1nica, ya que los PDI se revelaron como excelentes materiales transportadores de electrones con altas afinidades electr\u00f3nicas. Como consecuencia de todo lo anterior, se han estudiado exhaustivamente en c\u00e9lulas solares (org\u00e1nicas, sensibilizadas por colorantes y basadas en perovskitas), dispositivos emisores de luz, l\u00e1seres, transistores de efecto campo, sistemas fotosint\u00e9ticos artificiales, sensores y en diferentes aplicaciones biol\u00f3gicas.<\/p>\n

[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row padding_mobile=”off” column_padding_mobile=”on” admin_label=”row” _builder_version=”3.25″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” max_width=”860px” make_fullwidth=”off” use_custom_width=”on” width_unit=”on” custom_width_px=”860px”][et_pb_column type=”4_4″ _builder_version=”3.25″ custom_padding=”|||” custom_padding__hover=”|||”][et_pb_text admin_label=”Texto” _builder_version=”4.2.2″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” use_border_color=”off” border_color=”#ffffff” border_style=”solid”]<\/p>\n

Dise\u00f1o Molecular<\/a><\/h2>\n

Nuestro principal objetivo es la s\u00edntesis y organizaci\u00f3n supramolecular de sistemas electroactivos basados en ftalocianinas (Pcs) y dicetopirrolos (DPPs) como sistemas fotosint\u00e9ticos artificiales, para el tratamiento molecular fotovoltaico y anticanceroso.
\nLas Pcs son an\u00e1logos de las porfirinas con, generalmente, estructura planar y alta conjugaci\u00f3n del anillo central (18 \u03c0-electrones). Presentan propiedades interesantes para su aplicaci\u00f3n en c\u00e9lulas fotovoltaicas, especialmente una fuerte absorbencia en la regi\u00f3n de la radiaci\u00f3n visible e infrarroja cercana y una alta estabilidad t\u00e9rmica y qu\u00edmica. Por otro lado, los DPP poseen propiedades de absorbencia excepcionales en la regi\u00f3n de 500-600 nm, un fuerte rendimiento fluorescente adem\u00e1s de una gran estabilidad. Una caracter\u00edstica com\u00fan de los materiales basados en DPP es su potencial de oxidaci\u00f3n relativamente alto, que da lugar a estados de separaci\u00f3n de carga de alta energ\u00eda cuando se combinan con sistemas aceptores y, en consecuencia, se obtienen altos voltajes en las c\u00e9lulas solares. Por estas razones, los DPP, ya sea como pol\u00edmeros o como mol\u00e9culas individuales, est\u00e1n siendo investigados como capa activa en diferentes dispositivos OPV.<\/p>\n

[\/et_pb_text][\/et_pb_column][\/et_pb_row][\/et_pb_section][et_pb_section fb_built=”1″ fullwidth=”on” disabled_on=”off|off|off” admin_label=”Secci\u00f3n” _builder_version=”3.22″][et_pb_fullwidth_header title=”ORGANIC CHEMISTRY UNIT” text_orientation=”center” content_max_width=”none” admin_label=”T\u00edtulo de anchura completa” _builder_version=”3.16″ background_color=”#26aa9f” button_one_letter_spacing_hover=”0″ button_two_letter_spacing_hover=”0″ button_one_text_size__hover_enabled=”off” button_two_text_size__hover_enabled=”off” button_one_text_color__hover_enabled=”off” button_two_text_color__hover_enabled=”off” button_one_border_width__hover_enabled=”off” button_two_border_width__hover_enabled=”off” button_one_border_color__hover_enabled=”off” button_two_border_color__hover_enabled=”off” button_one_border_radius__hover_enabled=”off” button_two_border_radius__hover_enabled=”off” button_one_letter_spacing__hover_enabled=”on” button_one_letter_spacing__hover=”0″ button_two_letter_spacing__hover_enabled=”on” button_two_letter_spacing__hover=”0″ button_one_bg_color__hover_enabled=”off” button_two_bg_color__hover_enabled=”off”] [\/et_pb_fullwidth_header][\/et_pb_section][et_pb_section fb_built=”1″ disabled_on=”off|off|off” admin_label=”section” _builder_version=”3.22″][et_pb_row padding_mobile=”off” column_padding_mobile=”on” admin_label=”Fila” _builder_version=”4.2.2″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” make_fullwidth=”off” use_custom_width=”on” width_unit=”on” custom_width_px=”960px”][et_pb_column type=”4_4″ _builder_version=”3.25″ custom_padding=”|||” custom_padding__hover=”|||”][et_pb_text admin_label=”Texto” _builder_version=”3.27.4″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” use_border_color=”off” border_color=”#ffffff” border_style=”solid”]The Organic Chemistry Unit is devoted to the synthesis of organic molecules with optoelectronic and\/or biothecnological applications. With this purpose in mind, we use several scaffolds like phthalocyanines, perylenediimides, diketopyrrolopyrroles, fullerenes, nanotubes and other carbon nanoforms, graphene, MoS2\u2026 which after structural modification are transformed into valuable building blocks for the preparation of organic or hybrid solar cells, artificial photosynthetic systems, organic dye lasers, sensors, dual imaging agents, metallodrugs\u2026[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row padding_mobile=”off” column_padding_mobile=”on” admin_label=”Fila” _builder_version=”4.2.2″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” max_width=”860px” hover_enabled=”0″ make_fullwidth=”off” use_custom_width=”on” width_unit=”on” custom_width_px=”860px”][et_pb_column type=”4_4″ _builder_version=”3.25″ custom_padding=”|||” custom_padding__hover=”|||”][et_pb_text admin_label=”Texto” _builder_version=”3.27.4″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” hover_enabled=”0″ use_border_color=”off” border_color=”#ffffff” border_style=”solid”]<\/p>\n\n\n\n\n
Unit Coordinator<\/strong><\/td>\nFernando Fern\u00e1ndez L\u00e1zaro<\/td>\n<\/tr>\n
Contact<\/strong><\/strong><\/td>\nfdofdez@umh.es<\/span><\/strong><\/a><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row padding_mobile=”off” column_padding_mobile=”on” admin_label=”Fila” _builder_version=”4.2.2″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” make_fullwidth=”off” use_custom_width=”on” width_unit=”on” custom_width_px=”960px”][et_pb_column type=”4_4″ _builder_version=”3.25″ custom_padding=”|||” custom_padding__hover=”|||”][et_pb_text admin_label=”Texto” _builder_version=”4.2.2″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” use_border_color=”off” border_color=”#ffffff” border_style=”solid”]<\/p>\n

GROUPS<\/strong><\/h2>\n

The BioEngineering Institute of the Miguel Hern\u00e1ndez University has different groups of Organic Chemistry:<\/p>\n

[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row padding_mobile=”off” column_padding_mobile=”on” admin_label=”row” _builder_version=”4.2.2″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” make_fullwidth=”off” use_custom_width=”on” width_unit=”on” custom_width_px=”860px”][et_pb_column type=”4_4″ _builder_version=”3.25″ custom_padding=”|||” custom_padding__hover=”|||”][et_pb_text admin_label=”Texto” _builder_version=”4.2.2″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” use_border_color=”off” border_color=”#ffffff” border_style=”solid”]<\/p>\n

Molecular Synthesis<\/a><\/span><\/h2>\n

Since their discovery, perylenediimides (PDIs) have attracted much attention thanks to their strong absorption of visible light, their high fluorescence quantum yields and their thermal, chemical and photochemical stabilities. Another turn of the screw occurred with the advent of the organic optoelectronics, as PDIs revealed themselves as excellent electron transporting materials with high electron affinities. As a result of all the above, they have been exhaustively studied in solar cells (organic, dye-sensitized and perovskite-based), light-emitting devices, lasers, field-effect transistors, artificial photosynthetic systems, sensors and in different biological applications.<\/span><\/strong><\/p>\n

[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row padding_mobile=”off” column_padding_mobile=”on” admin_label=”row” _builder_version=”4.2.2″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” make_fullwidth=”off” use_custom_width=”on” width_unit=”on” custom_width_px=”860px”][et_pb_column type=”4_4″ _builder_version=”3.25″ custom_padding=”|||” custom_padding__hover=”|||”][et_pb_text admin_label=”Texto” _builder_version=”4.2.2″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” use_border_color=”off” border_color=”#ffffff” border_style=”solid”]<\/p>\n

Molecular Design<\/span><\/a><\/h2>\n

Our principal objective is the synthesis and supramolecular organization of electroactive systems based on phthalocyanines (Pcs) and dicetopyrrolopyrroles (DPPs) as artificial Photosynthetic Systems, for molecular Photovoltaic and Anticancer Treatment.
Pcs are porphyrin analogues with, generally, planar structure and high conjugation of the central ring (18 \u03c0-electrons). They present interesting properties for application in photovoltaic cells, especially strong absorbance in the visible and near infrared radiation region and high thermal and chemical stabilities. On the other hand, DPPs possess exceptional absorbance properties in the 500-600 nm region, strong fluorescent performance besides a great stability. A common feature of DPP-based materials is their relatively high oxidation potential, leading to high-energy charge-separated states when combined with acceptor systems and correspondingly high voltages are obtained in solar cells. For these reasons DPPs, either as polymers or as single molecules, are being investigated as active layer on different OPV devices.<\/p>\n

[\/et_pb_text][\/et_pb_column][\/et_pb_row][\/et_pb_section][et_pb_section fb_built=”1″ disabled_on=”on|on|on” _builder_version=”4.2.2″ disabled=”on”][et_pb_row _builder_version=”4.2.2″][et_pb_column type=”4_4″ _builder_version=”4.2.2″][:es _i=”0″ _address=”4.0.0.0″ \/][:en _i=”1″ _address=”4.0.0.1″ \/][: _i=”2″ _address=”4.0.0.2″ \/][\/et_pb_column][\/et_pb_row][\/et_pb_section]<\/p>\n","protected":false},"excerpt":{"rendered":"

La Unidad de Qu\u00edmica Org\u00e1nica se dedica a la s\u00edntesis de mol\u00e9culas org\u00e1nicas con aplicaciones optoelectr\u00f3nicas y\/o biotecnol\u00f3gicas. Con este fin, utilizamos diversos andamios como ftalocianinas, perilendiimidas, diketopirropirrolos, fullerenos, nanotubos y otras nanoformas de carbono, grafeno, MoS2… que tras su modificaci\u00f3n estructural se transforman en valiosos bloques de construcci\u00f3n para la preparaci\u00f3n de c\u00e9lulas solares […]<\/p>\n","protected":false},"author":17017,"featured_media":0,"parent":0,"menu_order":69,"comment_status":"open","ping_status":"open","template":"","meta":{"_et_pb_use_builder":"on","_et_pb_old_content":"","_et_gb_content_width":"","_links_to":"","_links_to_target":""},"_links":{"self":[{"href":"https:\/\/bioingenieria.umh.es\/en\/wp-json\/wp\/v2\/pages\/4261"}],"collection":[{"href":"https:\/\/bioingenieria.umh.es\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/bioingenieria.umh.es\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/bioingenieria.umh.es\/en\/wp-json\/wp\/v2\/users\/17017"}],"replies":[{"embeddable":true,"href":"https:\/\/bioingenieria.umh.es\/en\/wp-json\/wp\/v2\/comments?post=4261"}],"version-history":[{"count":0,"href":"https:\/\/bioingenieria.umh.es\/en\/wp-json\/wp\/v2\/pages\/4261\/revisions"}],"wp:attachment":[{"href":"https:\/\/bioingenieria.umh.es\/en\/wp-json\/wp\/v2\/media?parent=4261"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}