{"id":4525,"date":"2021-12-22T07:27:25","date_gmt":"2021-12-22T07:27:25","guid":{"rendered":"https:\/\/bioingenieria.zeus.umh.es\/grupo-de-sintesis-molecular\/"},"modified":"2022-03-23T11:44:25","modified_gmt":"2022-03-23T11:44:25","slug":"grupo-de-sintesis-molecular","status":"publish","type":"page","link":"https:\/\/bioingenieria.umh.es\/en\/unidad-de-quimica-organica\/grupo-de-sintesis-molecular\/","title":{"rendered":"Grupo de S\u00edntesis Molecular"},"content":{"rendered":"

[et_pb_section fb_built=”1″ fullwidth=”on” disabled_on=”on|on|on” admin_label=”Secci\u00f3n” _builder_version=”3.22″ disabled=”on”][et_pb_fullwidth_header title=”Grupo de S\u00edntesis Molecular” text_orientation=”center” content_max_width=”none” admin_label=”T\u00edtulo de anchura completa” _builder_version=”3.16″ background_color=”#649922″ button_one_letter_spacing_hover=”0″ button_two_letter_spacing_hover=”0″ button_one_text_size__hover_enabled=”off” button_two_text_size__hover_enabled=”off” button_one_text_color__hover_enabled=”off” button_two_text_color__hover_enabled=”off” button_one_border_width__hover_enabled=”off” button_two_border_width__hover_enabled=”off” button_one_border_color__hover_enabled=”off” button_two_border_color__hover_enabled=”off” button_one_border_radius__hover_enabled=”off” button_two_border_radius__hover_enabled=”off” button_one_letter_spacing__hover_enabled=”on” button_one_letter_spacing__hover=”0″ button_two_letter_spacing__hover_enabled=”on” button_two_letter_spacing__hover=”0″ button_one_bg_color__hover_enabled=”off” button_two_bg_color__hover_enabled=”off”][\/et_pb_fullwidth_header][\/et_pb_section][et_pb_section fb_built=”1″ disabled_on=”on|on|on” admin_label=”section” _builder_version=”3.22″ disabled=”on”][et_pb_row padding_mobile=”off” column_padding_mobile=”on” admin_label=”row” _builder_version=”3.25″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” max_width=”980px” make_fullwidth=”off” use_custom_width=”on” width_unit=”on” custom_width_px=”980px”][et_pb_column type=”4_4″ _builder_version=”3.25″ custom_padding=”|||” custom_padding__hover=”|||”][et_pb_tabs admin_label=”Pesta\u00f1as” _builder_version=”4.2.2″ tab_font=”Roboto||||” tab_line_height=”1.4em” background_size=”initial” background_position=”top_left” background_repeat=”repeat” use_border_color=”off” border_color=”#ffffff” border_style=”solid”][et_pb_tab title=”Informaci\u00f3n” _builder_version=”4.2.2″ body_font=”||||” body_line_height=”2em” tab_font=”||||” tab_line_height=”2em” background_size=”initial” background_position=”top_left” background_repeat=”repeat” body_line_height_tablet=”2em” body_line_height_phone=”2em” tab_line_height_tablet=”2em” tab_line_height_phone=”2em”]<\/p>\n\n\n\n\n
Responsable<\/strong><\/td>\nFernando Fern\u00e1ndez L\u00e1zaro<\/td>\n<\/tr>\n
Web propia<\/strong><\/td>\nhttp:\/\/quimicaorganica.umh.es<\/a><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

 <\/p>\n

RESUMEN DE LA INVESTIGACI\u00d3N<\/strong><\/h4>\n

Desde su descubrimiento, las perilendiimidas (PDI) han atra\u00eddo mucha atenci\u00f3n gracias a su fuerte absorci\u00f3n de la luz visible, sus elevados rendimientos cu\u00e1nticos de fluorescencia y su estabilidad t\u00e9rmica, qu\u00edmica y fotoqu\u00edmica. Otra vuelta de tuerca se produjo con la llegada de la optoelectr\u00f3nica org\u00e1nica, ya que los PDI se revelaron como excelentes materiales transportadores de electrones con altas afinidades electr\u00f3nicas. Como resultado de todo lo anterior, se han estudiado exhaustivamente en c\u00e9lulas solares (org\u00e1nicas, sensibilizadas por colorantes y basadas en perovskitas), dispositivos emisores de luz, l\u00e1seres, transistores de efecto de campo, sistemas fotosint\u00e9ticos artificiales, sensores y en diferentes aplicaciones biol\u00f3gicas.<\/p>\n

\"s\u00edntesis<\/a><\/p>\n

Esquema de un LED basado en PDI preparado en nuestro grupo.<\/span><\/strong><\/em><\/p>\n

 <\/p>\n

L\u00cdNEAS DE INVESTIGACI\u00d3N<\/strong><\/h4>\n

 <\/p>\n

L\u00ednea 1:\u00a0Nuevos m\u00e9todos de s\u00edntesis y modificaci\u00f3n de perilendiimidas<\/strong><\/h4>\n

La gran variedad de aplicaciones de las PDIs requiere el ajuste del empaquetamiento molecular y de las propiedades \u00f3pticas y electr\u00f3nicas, lo que puede lograrse mediante la introducci\u00f3n de sustituyentes adecuados en su estructura. En nuestro grupo estamos interesados en la b\u00fasqueda de nuevas y m\u00e1s eficientes formas de modificar la estructura qu\u00edmica de las PDIs, permitiendo as\u00ed la adaptaci\u00f3n de las propiedades para la aplicaci\u00f3n deseada.<\/p>\n

\"s\u00edntesis<\/p>\n

La introducci\u00f3n de los sustituyentes adecuados en el andamio de la PDI permite modificar las propiedades de las PDI como, por ejemplo, el espectro de absorci\u00f3n y, por tanto, el color en soluci\u00f3n.<\/span><\/strong><\/em><\/p>\n

 <\/p>\n

L\u00ednea 2:\u00a0Tintes org\u00e1nicos para l\u00e1ser<\/strong><\/h4>\n

Los PDIs representan una excelente opci\u00f3n para los l\u00e1seres org\u00e1nicos porque no s\u00f3lo presentan buenas propiedades de emisi\u00f3n y sintonizaci\u00f3n de longitudes de onda, sino tambi\u00e9n una buena estabilidad t\u00e9rmica y \u00f3ptica y una alta movilidad de los electrones. Adem\u00e1s, las propiedades \u00f3pticas y electr\u00f3nicas de los PDI pueden adaptarse introduciendo los sustituyentes adecuados, lo que da lugar a l\u00e1seres de estado s\u00f3lido de alto rendimiento.<\/p>\n

\u00a0\"s\u00edntesis<\/p>\n

Esquema de un l\u00e1ser preparado con uno de nuestros PDI.<\/span><\/strong><\/em><\/p>\n

 <\/p>\n

L\u00ednea 3:\u00a0S\u00edntesis de materiales org\u00e1nicos para la fotovoltaica<\/strong><\/h4>\n

Nuestro grupo trabaja activamente en la incorporaci\u00f3n de perilendiimidas como componentes fotoactivos en diferentes dispositivos de c\u00e9lulas solares: c\u00e9lulas solares org\u00e1nicas p-n, como aceptores de no-fullereno en c\u00e9lulas solares de heterouni\u00f3n masiva, como fotosensibilizadores en c\u00e9lulas solares sensibilizadas por colorantes, en c\u00e9lulas solares de perovskita, y tambi\u00e9n como intercalares que act\u00faan como materiales transportadores de electrones o de huecos. Como paso previo, investigamos las propiedades fotof\u00edsicas de los PDI en relaci\u00f3n con la transferencia de energ\u00eda y\/o electrones fotoinducida. Tambi\u00e9n estamos interesados en el uso de PDIs en sistemas fotosint\u00e9ticos artificiales.<\/p>\n

\"s\u00edntesis<\/p>\n

[\/et_pb_tab][et_pb_tab title=”Miembros” _builder_version=”4.2.2″ body_font=”Roboto||||” body_line_height=”2em” tab_font=”Roboto||||” tab_line_height=”2em” background_size=”initial” background_position=”top_left” background_repeat=”repeat” body_line_height_tablet=”2em” body_line_height_phone=”2em” tab_line_height_tablet=”2em” tab_line_height_phone=”2em”]<\/p>\n\n\n\n\n\n\n\n\n
Nombre<\/strong><\/td>\nPuesto<\/strong><\/td>\nCorreo<\/strong><\/td>\nORCID<\/strong><\/td>\n<\/tr>\n
Fernando Fern\u00e1ndez L\u00e1zaro<\/td>\nCatadr\u00e1tico de Universidad<\/td>\nfdofdez@umh.es<\/a><\/td>\n0000-0002-4598-6024<\/td>\n<\/tr>\n
Enrique Font Sanchis<\/td>\nProfesor Titular de Universidad<\/td>\nenrique.font@umh.es<\/a><\/td>\n0000-0002-5082-3107<\/td>\n<\/tr>\n
Ana Mar\u00eda Guti\u00e9rrez V\u00edlchez<\/td>\nProfesora Contratada Doctora<\/td>\nanavil@umh.es<\/a><\/td>\n0000-0002-9310-4022<\/td>\n<\/tr>\n
Nathalie Zink Lorre<\/td>\nProfesora Ayudante Doctora<\/span><\/strong><\/td>\nnzink@umh.es<\/a><\/td>\n0000-0003-3081-995X<\/td>\n<\/tr>\n
Jose Garc\u00e9s Garc\u00e9s<\/td>\nDoctorando<\/td>\njgarces@umh.es<\/a><\/td>\n0000-0002-7637-3140<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\"s\u00edntesis<\/a><\/p>\n

[\/et_pb_tab][et_pb_tab title=”Publicaciones” _builder_version=”4.2.2″ body_font=”Roboto||||” body_line_height=”2em” tab_font=”Roboto||||” tab_line_height=”2em” background_size=”initial” background_position=”top_left” background_repeat=”repeat” body_line_height_tablet=”2em” body_line_height_phone=”2em” tab_line_height_tablet=”2em” tab_line_height_phone=”2em”]<\/p>\n

A. Scalabre, A. M. Guti\u00e9rrez-V\u00edlchez, \u00c1. Sastre-Santos, F. Fern\u00e1ndez-L\u00e1zaro, D. M. Bassani y R. Oda
Supramolecular Induction of Topological Chirality fron Nanoscale Helical Silica Scaffolds to Achiral Molecular Chromophores<\/a><\/strong>
J. Phys. Chem. C 124, 23839-23843 (2020)<\/p>\n

I. Papadopoulos, D. Guti\u00e9rrez-Moreno, P. M. McCosker, R. Casillas, P. A. Keller, \u00c1. Sastre-Santos, T. Clark, F. Fern\u00e1ndez-L\u00e1zaro y D. M. Guldi
Perylene-Monoimides: Singlet Fission Down-Conversion Competes with Up-Conversion by Geminate Triplet-Triplet Recombination<\/strong><\/a>
J. Phys. Chem. A 124, 5727\u20135736 (2020)<\/p>\n

E. J. Canto-Aguilar, D. Guti\u00e9rrez-Moreno, \u00c1. Sastre-Santos, D. Morikawa, M. Abe, F. Fern\u00e1ndez-L\u00e1zaro, G. Oskam y S. Mori.
Identification of the Loss Mechanisms in TiO2 and ZnO Solar Cells Based on Blue, Piperidinyl-Substituted, Mono-Anhydride Perylene Dyes<\/strong><\/a>
Electrochim. 355, 136638 1-11 (2020)<\/p>\n

N. Zink-Lorre, E. Font-Sanchis, \u00c1. Sastre-Santos y F. Fern\u00e1ndez-L\u00e1zaro
Perylenediimides as More than Just Non-Fullerene Acceptors: Versatile Components in Organic, Hybrid and Perovskite Solar Cells<\/strong><\/a>
Chem. Commun. 56, 3824-3838 (2020)<\/p>\n

V. Navarro-P\u00e9rez, A. M. Guti\u00e9rrez-V\u00edlchez, J. Ortiz, \u00c1. Sastre-Santos, F. Fern\u00e1ndez-L\u00e1zaro, S. Seetharaman, M. J. Duffy, P. A. Karr y F. D\u2019Souza
A Zinc Phthalocyanine-Benzoperylenetriimide Conjugate for Solvent Dependent Ultrafast Energy vs. Electron Transfer<\/strong><\/a>
Chem. Commun. 55, 14946-14949 (2019)<\/p>\n

N. Zink-Lorre, A. Doncel-Gim\u00e9nez, E. Font-Sanchis, J. Calbo, A. Sastre-Santos, E. Ort\u00ed y F. Fern\u00e1ndez-L\u00e1zaro
Diels-Alder Reaction on Perylenediimides: Synthesis and Theoretical Study of Core-Expanded Diimides<\/strong><\/a>
Org. Chem. Front. 6, 2860-2871 (2019)<\/p>\n

D. Guti\u00e9rrez-Moreno, A. Sastre-Santos y F. Fern\u00e1ndez-L\u00e1zaro
Direct Amination and N-Heteroarylation of Perylenediimides<\/strong><\/a>
Org. Chem. Front. 6, 2488-2499 (2019)<\/p>\n

N. Zink-Lorre, E. Font-Sanchis, S. Seetharaman, P. A. Karr, A. Sastre-Santos, F. D\u2019Souza y F. Fern\u00e1ndez-L\u00e1zaro
Directly Linked Zinc Phthalocyanine-Perylenediimide Dyads and a Triad for Ultrafast Charge Separation<\/strong><\/a>
Chem.-Eur. J. 25, 10123-10132 (2019)<\/p>\n

R. Mu\u00f1oz-M\u00e1rmol, N. Zink-Lorre, J. M. Villalvilla, P. G. Boj, J. A. Quintana, C. V\u00e1zquez, A. Anderson, M. J. Gordon, \u00c1. Sastre-Santos, F. Fern\u00e1ndez-L\u00e1zaro y M. A. D\u00edaz-Garc\u00eda
Influence of Blending Ratio and Polymer Matrix on the Lasing Properties of Perylenediimide Dyes<\/strong><\/a>
J. Phys. Chem. C 122, 24896-24906 (2018)<\/p>\n

D. Guti\u00e9rrez-Moreno, \u00c1. Sastre-Santos y F. Fern\u00e1ndez-L\u00e1zaro
Synthesis of Bay-Triaminosubstituted Perylenediimides<\/strong><\/a>
Org. Chem. Front. 5, 1830-1834 (2018)<\/p>\n

[\/et_pb_tab][et_pb_tab title=”Proyectos” _builder_version=”4.2.2″ body_font=”||||” body_line_height=”2em” tab_font=”||||” tab_line_height=”2em” background_size=”initial” background_position=”top_left” background_repeat=”repeat” body_line_height_tablet=”2em” body_line_height_phone=”2em” tab_line_height_tablet=”2em” tab_line_height_phone=”2em”]<\/p>\n

 <\/p>\n

Perilenodiimidas: transferencia electr\u00f3nica fotoinducida en sistemas multicromof\u00f3ricos, fisi\u00f3n singlete y l\u00e1seres. Preparaci\u00f3n de SURMOF basados en PDI. (PID2019-109200GB-I00). Agencia de financiaci\u00f3n: Agencia Estatal de Investigaci\u00f3n \/ Ministerio de Ciencia e Innovaci\u00f3n. Vigencia: 01\/06\/2020-31\/05\/2023.
PI: Fernando Fern\u00e1ndez L\u00e1zaro<\/em><\/p>\n

\n

Perilenodiimidas para dispositivos fotovoltaicos y para l\u00e1seres. Estudio del aumento de la conjugaci\u00f3n de perilenodiimidas. (CTQ2016-77039-R). Agencia de financiaci\u00f3n: Ministerio de Econom\u00eda, Industria y Competitividad. Vigencia: 30\/12\/2016-31\/12\/2020.
PI: Fernando Fern\u00e1ndez L\u00e1zaro<\/em><\/p>\n

\n

S\u00edntesis de perilenodiimidas para c\u00e9lulas solares org\u00e1nicas. Estudio de reactividad de perilenodiimidas y aplicaci\u00f3n en sondas fluorog\u00e9nicas. (CTQ2013-47922-R). Agencia de financiaci\u00f3n: Ministerio de Econom\u00eda y Competitividad. Vigencia: 1\/01\/2014-30\/06\/2017.
PI: Fernando Fern\u00e1ndez L\u00e1zaro<\/em><\/p>\n

\n

Perilenos y perilenos pi-extendidos: aplicaciones en dispositivos fotovoltaicos, diodos emisores de luz, cristales l\u00edquidos y biomarcadores. (CTQ2010-20349). Agencia de financiaci\u00f3n: Ministerio de Ciencia e Innovaci\u00f3n. Vigencia: 1\/01\/2011-30\/09\/2014.
PI: Fernando Fern\u00e1ndez L\u00e1zaro<\/em><\/p>\n

\n

S\u00edntesis de compuestos fotoactivos y fotoemisores para la preparaci\u00f3n de c\u00e9lulas solares org\u00e1nicas y diodos emisores de luz org\u00e1nicos. (CTQ2007-67888\/BQU). Agencia de financiaci\u00f3n: Ministerio de Educaci\u00f3n y Ciencia. Vigencia: 1\/10\/2007-30\/12\/2010.
PI: Fernando Fern\u00e1ndez L\u00e1zaro<\/em><\/p>\n

[\/et_pb_tab][\/et_pb_tabs][\/et_pb_column][\/et_pb_row][\/et_pb_section][et_pb_section fb_built=”1″ fullwidth=”on” disabled_on=”off|off|off” admin_label=”Secci\u00f3n” _builder_version=”3.22″][et_pb_fullwidth_header title=”Molecular Synthesis Group” text_orientation=”center” content_max_width=”none” admin_label=”T\u00edtulo de anchura completa” _builder_version=”3.16″ background_color=”#649922″ button_one_letter_spacing_hover=”0″ button_two_letter_spacing_hover=”0″ button_one_text_size__hover_enabled=”off” button_two_text_size__hover_enabled=”off” button_one_text_color__hover_enabled=”off” button_two_text_color__hover_enabled=”off” button_one_border_width__hover_enabled=”off” button_two_border_width__hover_enabled=”off” button_one_border_color__hover_enabled=”off” button_two_border_color__hover_enabled=”off” button_one_border_radius__hover_enabled=”off” button_two_border_radius__hover_enabled=”off” button_one_letter_spacing__hover_enabled=”on” button_one_letter_spacing__hover=”0″ button_two_letter_spacing__hover_enabled=”on” button_two_letter_spacing__hover=”0″ button_one_bg_color__hover_enabled=”off” button_two_bg_color__hover_enabled=”off”][\/et_pb_fullwidth_header][\/et_pb_section][et_pb_section fb_built=”1″ disabled_on=”off|off|off” admin_label=”section” _builder_version=”3.22″][et_pb_row padding_mobile=”off” column_padding_mobile=”on” admin_label=”row” _builder_version=”3.25″ background_size=”initial” background_position=”top_left” background_repeat=”repeat” max_width=”980px” make_fullwidth=”off” use_custom_width=”on” width_unit=”on” custom_width_px=”980px”][et_pb_column type=”4_4″ _builder_version=”3.25″ custom_padding=”|||” custom_padding__hover=”|||”][et_pb_tabs admin_label=”Pesta\u00f1as” _builder_version=”4.2.2″ tab_font=”Roboto||||” tab_line_height=”1.4em” background_size=”initial” background_position=”top_left” background_repeat=”repeat” hover_enabled=”0″ use_border_color=”off” border_color=”#ffffff” border_style=”solid”][et_pb_tab title=”Information” _builder_version=”4.2.2″ body_font=”||||” body_line_height=”2em” tab_font=”||||” tab_line_height=”2em” background_size=”initial” background_position=”top_left” background_repeat=”repeat” body_line_height_tablet=”2em” body_line_height_phone=”2em” tab_line_height_tablet=”2em” tab_line_height_phone=”2em”]<\/p>\n\n\n\n\n
Responsible<\/strong><\/td>\nFernando Fern\u00e1ndez L\u00e1zaro<\/td>\n<\/tr>\n
Website<\/strong><\/td>\nhttp:\/\/quimicaorganica.umh.es<\/a><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

 <\/p>\n

RESEARCH SUMMARY<\/strong><\/h4>\n

Since their discovery, perylenediimides (PDIs) have attracted much attention thanks to their strong absorption of visible light, their high fluorescence quantum yields and their thermal, chemical and photochemical stabilities. Another turn of the screw occurred with the advent of the organic optoelectronics, as PDIs revealed themselves as excellent electron transporting materials with high electron affinities. As a result of all the above, they have been exhaustively studied in solar cells (organic, dye-sensitized and perovskite-based), light-emitting devices, lasers, field-effect transistors, artificial photosynthetic systems, sensors and in different biological applications.<\/span><\/strong><\/p>\n

\"s\u00edntesis<\/a><\/p>\n

Scheme of a PDI-based LED prepared in our group.<\/span><\/strong><\/em><\/p>\n

 <\/p>\n

RESEARCH LINES<\/strong><\/h4>\n

 <\/p>\n

Line1: New methods for synthesis and modification of perylenediimides<\/strong><\/h4>\n

The wide variety of applications of PDIs requires the fine-tuning of the molecular packing and the optical and electronic properties, which may be accomplished by introduction of suitable substituents in their structure. In our group we are interested in the search for new and more efficient ways to modify the chemical structure of PDIs, thus allowing the tailoring of the properties for the desired application.<\/span><\/strong><\/p>\n

\"s\u00edntesis<\/p>\n

The introduction of the adequate substituents on the PDI scaffold allows for the modification of the properties of PDIs as, for example, the absorption spectrum and, hence, the colour in solution.<\/span><\/strong><\/em><\/p>\n

 <\/p>\n

Line 2: Organic laser dyes<\/strong><\/h4>\n

PDIs represent an outstanding choice for organic lasers because they exhibit not only good emission properties and wavelength tunability, but also good thermal and optical stabilities and high electron mobility. In addition, optical and electronic properties of PDIs can be tailored by introducing the adequate substituents, resulting in high-performance solid state lasers.<\/span><\/strong><\/p>\n

\u00a0\"s\u00edntesis<\/p>\n

Scheme of a laser prepared with one of our PDIs.<\/span><\/strong><\/em><\/p>\n

 <\/p>\n

Line 3:\u00a0Synthesis of organic materials for photovoltaics<\/strong><\/h4>\n

Our group is actively working in the incorporation of perylenediimides as photoactive components in different solar cell devices: p<\/i>–n<\/i> organic solar cells, as non-fullerene acceptors in bulk heterojunction solar cells, as photosensitisers in dye-sensitised solar cells, in perovskite solar cells, and also as interlayers acting as either electron- or hole-transporting materials. As a previous step, we investigate the photophysical properties of PDIs regarding to photoinduced energy and\/or electron transfer. We are also interested in the use of PDIs in artificial photosynthetic systems.<\/span><\/strong><\/p>\n

\"s\u00edntesis<\/p>\n

[\/et_pb_tab][et_pb_tab title=”Members” _builder_version=”4.2.2″ body_font=”Roboto||||” body_line_height=”2em” tab_font=”Roboto||||” tab_line_height=”2em” background_size=”initial” background_position=”top_left” background_repeat=”repeat” hover_enabled=”0″ body_line_height_tablet=”2em” body_line_height_phone=”2em” tab_line_height_tablet=”2em” tab_line_height_phone=”2em”]<\/p>\n\n\n\n\n\n\n\n\n
Name<\/strong><\/td>\nPosition<\/strong><\/td>\ne-mail<\/strong><\/td>\nORCID<\/strong><\/td>\n<\/tr>\n
Fernando Fern\u00e1ndez L\u00e1zaro<\/td>\nFull Professor<\/td>\nfdofdez@umh.es<\/a><\/td>\n0000-0002-4598-6024<\/td>\n<\/tr>\n
Enrique Font Sanchis<\/td>\nAssociate Professor<\/td>\nenrique.font@umh.es<\/a><\/td>\n0000-0002-5082-3107<\/td>\n<\/tr>\n
Ana Mar\u00eda Guti\u00e9rrez V\u00edlchez<\/td>\nPhD. Assistant Lecturer<\/td>\nanavil@umh.es<\/a><\/td>\n0000-0002-9310-4022<\/td>\n<\/tr>\n
Nathalie Zink Lorre<\/td>\nPhD. Assistant Lecturer<\/span><\/strong><\/td>\nnzink@umh.es<\/a><\/td>\n0000-0003-3081-995X<\/td>\n<\/tr>\n
Jose Garc\u00e9s Garc\u00e9s<\/td>\nPhD Student<\/td>\njgarces@umh.es<\/a><\/td>\n0000-0002-7637-3140<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\"\"<\/p>\n

[\/et_pb_tab][et_pb_tab title=”Publications” _builder_version=”4.2.2″ body_font=”Roboto||||” body_line_height=”2em” tab_font=”Roboto||||” tab_line_height=”2em” background_size=”initial” background_position=”top_left” background_repeat=”repeat” body_line_height_tablet=”2em” body_line_height_phone=”2em” tab_line_height_tablet=”2em” tab_line_height_phone=”2em”]<\/p>\n

A. Scalabre, A. M. Guti\u00e9rrez-V\u00edlchez, \u00c1. Sastre-Santos, F. Fern\u00e1ndez-L\u00e1zaro, D. M. Bassani y R. Oda
Supramolecular Induction of Topological Chirality fron Nanoscale Helical Silica Scaffolds to Achiral Molecular Chromophores<\/a><\/strong>
J. Phys. Chem. C 124, 23839-23843 (2020)<\/p>\n

I. Papadopoulos, D. Guti\u00e9rrez-Moreno, P. M. McCosker, R. Casillas, P. A. Keller, \u00c1. Sastre-Santos, T. Clark, F. Fern\u00e1ndez-L\u00e1zaro y D. M. Guldi
Perylene-Monoimides: Singlet Fission Down-Conversion Competes with Up-Conversion by Geminate Triplet-Triplet Recombination<\/strong><\/a>
J. Phys. Chem. A 124, 5727\u20135736 (2020)<\/p>\n

E. J. Canto-Aguilar, D. Guti\u00e9rrez-Moreno, \u00c1. Sastre-Santos, D. Morikawa, M. Abe, F. Fern\u00e1ndez-L\u00e1zaro, G. Oskam y S. Mori.
Identification of the Loss Mechanisms in TiO2 and ZnO Solar Cells Based on Blue, Piperidinyl-Substituted, Mono-Anhydride Perylene Dyes<\/strong><\/a>
Electrochim. 355, 136638 1-11 (2020)<\/p>\n

N. Zink-Lorre, E. Font-Sanchis, \u00c1. Sastre-Santos y F. Fern\u00e1ndez-L\u00e1zaro
Perylenediimides as More than Just Non-Fullerene Acceptors: Versatile Components in Organic, Hybrid and Perovskite Solar Cells<\/strong><\/a>
Chem. Commun. 56, 3824-3838 (2020)<\/p>\n

V. Navarro-P\u00e9rez, A. M. Guti\u00e9rrez-V\u00edlchez, J. Ortiz, \u00c1. Sastre-Santos, F. Fern\u00e1ndez-L\u00e1zaro, S. Seetharaman, M. J. Duffy, P. A. Karr y F. D\u2019Souza
A Zinc Phthalocyanine-Benzoperylenetriimide Conjugate for Solvent Dependent Ultrafast Energy vs. Electron Transfer<\/strong><\/a>
Chem. Commun. 55, 14946-14949 (2019)<\/p>\n

N. Zink-Lorre, A. Doncel-Gim\u00e9nez, E. Font-Sanchis, J. Calbo, A. Sastre-Santos, E. Ort\u00ed y F. Fern\u00e1ndez-L\u00e1zaro
Diels-Alder Reaction on Perylenediimides: Synthesis and Theoretical Study of Core-Expanded Diimides<\/strong><\/a>
Org. Chem. Front. 6, 2860-2871 (2019)<\/p>\n

D. Guti\u00e9rrez-Moreno, A. Sastre-Santos y F. Fern\u00e1ndez-L\u00e1zaro
Direct Amination and N-Heteroarylation of Perylenediimides<\/strong><\/a>
Org. Chem. Front. 6, 2488-2499 (2019)<\/p>\n

N. Zink-Lorre, E. Font-Sanchis, S. Seetharaman, P. A. Karr, A. Sastre-Santos, F. D\u2019Souza y F. Fern\u00e1ndez-L\u00e1zaro
Directly Linked Zinc Phthalocyanine-Perylenediimide Dyads and a Triad for Ultrafast Charge Separation<\/strong><\/a>
Chem.-Eur. J. 25, 10123-10132 (2019)<\/p>\n

R. Mu\u00f1oz-M\u00e1rmol, N. Zink-Lorre, J. M. Villalvilla, P. G. Boj, J. A. Quintana, C. V\u00e1zquez, A. Anderson, M. J. Gordon, \u00c1. Sastre-Santos, F. Fern\u00e1ndez-L\u00e1zaro y M. A. D\u00edaz-Garc\u00eda
Influence of Blending Ratio and Polymer Matrix on the Lasing Properties of Perylenediimide Dyes<\/strong><\/a>
J. Phys. Chem. C 122, 24896-24906 (2018)<\/p>\n

D. Guti\u00e9rrez-Moreno, \u00c1. Sastre-Santos y F. Fern\u00e1ndez-L\u00e1zaro
Synthesis of Bay-Triaminosubstituted Perylenediimides<\/strong><\/a>
Org. Chem. Front. 5, 1830-1834 (2018)<\/p>\n

[\/et_pb_tab][et_pb_tab title=”Projects” _builder_version=”3.0.48″ body_font=”||||” body_line_height=”2em” tab_font=”||||” tab_line_height=”2em” background_size=”initial” background_position=”top_left” background_repeat=”repeat” body_line_height_tablet=”2em” body_line_height_phone=”2em” tab_line_height_tablet=”2em” tab_line_height_phone=”2em”]<\/p>\n

Perylene diamides: photoinduced electron transfer in multichromophoric systems, singlet fission and lasers. Preparation of PDI-based SURMOFs. (PID2019-109200GB-I00). Funding agency: State Research Agency \/ Ministry of Science and Innovation. Duration: 01\/06\/2020-31\/05\/2023.<\/p>\n

PI: Fernando Fern\u00e1ndez L\u00e1zaro<\/em><\/p>\n

\n

Perylene diamides for photovoltaic devices and lasers. Study of the conjugation enhancement of perylenediimides. (CTQ2016-77039-R). Funding agency: Ministry of Economy, Industry and Competitiveness. Duration: 30\/12\/2016-31\/12\/2020.<\/p>\n

PI: Fernando Fern\u00e1ndez L\u00e1zaro<\/em><\/p>\n

\n

Synthesis of perylene diamides for organic solar cells. Reactivity study of perylenediimides and application in fluorogenic probes. (CTQ2013-47922-R). Funding agency: Ministry of Economy and Competitiveness. Duration: 1\/01\/2014-30\/06\/2017.<\/p>\n

PI: Fernando Fern\u00e1ndez L\u00e1zaro<\/em><\/p>\n

\n

Perylenes and pi-extended perylenes: applications in photovoltaic devices, light-emitting diodes, liquid crystals and biomarkers. (CTQ2010-20349). Funding agency: Ministry of Science and Innovation. Duration: 1\/01\/2011-30\/09\/2014.<\/p>\n

PI: Fernando Fern\u00e1ndez L\u00e1zaro<\/em><\/p>\n

\n

Synthesis of photoactive compounds and photoemitters for the preparation of organic solar cells and organic light-emitting diodes. (CTQ2007-67888\/BQU). Funding agency: Ministry of Education and Science. Duration: 1\/10\/2007-30\/12\/2010.<\/p>\n

PI: Fernando Fern\u00e1ndez L\u00e1zaro<\/em><\/p>\n

[\/et_pb_tab][\/et_pb_tabs][\/et_pb_column][\/et_pb_row][\/et_pb_section][et_pb_section fb_built=”1″ disabled_on=”on|on|on” _builder_version=”4.2.2″ disabled=”on”][et_pb_row _builder_version=”4.2.2″][et_pb_column type=”4_4″ _builder_version=”4.2.2″][:es _i=”0″ _address=”4.0.0.0″ \/][:en _i=”1″ _address=”4.0.0.1″ \/][: _i=”2″ _address=”4.0.0.2″ \/][\/et_pb_column][\/et_pb_row][\/et_pb_section]<\/p>\n","protected":false},"excerpt":{"rendered":"

Responsable Fernando Fern\u00e1ndez L\u00e1zaro Web propia http:\/\/quimicaorganica.umh.es   RESUMEN DE LA INVESTIGACI\u00d3N Desde su descubrimiento, las perilendiimidas (PDI) han atra\u00eddo mucha atenci\u00f3n gracias a su fuerte absorci\u00f3n de la luz visible, sus elevados rendimientos cu\u00e1nticos de fluorescencia y su estabilidad t\u00e9rmica, qu\u00edmica y fotoqu\u00edmica. Otra vuelta de tuerca se produjo con la llegada de la […]<\/p>\n","protected":false},"author":17017,"featured_media":0,"parent":4261,"menu_order":70,"comment_status":"open","ping_status":"closed","template":"","meta":{"_et_pb_use_builder":"on","_et_pb_old_content":"","_et_gb_content_width":"","_links_to":"","_links_to_target":""},"_links":{"self":[{"href":"https:\/\/bioingenieria.umh.es\/en\/wp-json\/wp\/v2\/pages\/4525"}],"collection":[{"href":"https:\/\/bioingenieria.umh.es\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/bioingenieria.umh.es\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/bioingenieria.umh.es\/en\/wp-json\/wp\/v2\/users\/17017"}],"replies":[{"embeddable":true,"href":"https:\/\/bioingenieria.umh.es\/en\/wp-json\/wp\/v2\/comments?post=4525"}],"version-history":[{"count":0,"href":"https:\/\/bioingenieria.umh.es\/en\/wp-json\/wp\/v2\/pages\/4525\/revisions"}],"up":[{"embeddable":true,"href":"https:\/\/bioingenieria.umh.es\/en\/wp-json\/wp\/v2\/pages\/4261"}],"wp:attachment":[{"href":"https:\/\/bioingenieria.umh.es\/en\/wp-json\/wp\/v2\/media?parent=4525"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}